Radical Chemistry
Chemistry
Institute of Natural and Applied Sciences
Third Cycle (Doctorate Degree)
| Course Unit Title | Course Unit Code | Type of Course Unit | Level of Course Unit | Year of Study | Semester | ECTS Credits |
|---|---|---|---|---|---|---|
| Radical Chemistry | KIM612 | Elective | Doctorate degree | 1 | Spring | 8 |
Name of Lecturer(s)
Prof. Dr. Mehmet YILMAZ
Learning Outcomes of the Course Unit
1) clssify radicals
2) synthesis radicals
3) use radicals in organik reactions
4) Form carbon-carbon bond
5) Form C-N bond
Program Competencies-Learning Outcomes Relation
| Program Competencies | |||||
| 1 | 2 | 3 | 4 | ||
| Learning Outcomes | |||||
| 1 | Middle | No relation | No relation | No relation | |
| 2 | Middle | No relation | No relation | No relation | |
| 3 | Middle | No relation | No relation | No relation | |
| 4 | Middle | No relation | No relation | No relation | |
| 5 | Middle | No relation | No relation | No relation | |
Mode of Delivery
Face to Face
Prerequisites and Co-Requisites
None
Recommended Optional Programme Components
organic chemistry-1 organic chemistry-2 organic reaction mechanism
Course Contents
electron migration on organic structures. basic tereochemistry for organic reactions. properties of radicals. Preparation of radicals. Radical elimination reactions. Radical additions. radical coupling and disproportion reactions. Single electron transfer reactions. Birch reduction. Reargement of di-pi-methane. Diazo compounds and diradicals. Functional group conversion. intramoleculer radical cyclization. intermolecular radical cyclization. alkylation of aromatics. free radical reactions with metal hydrides.
Weekly Schedule
1) properties of radicals2) preparation of radicals
3) - structral analysis of radicals. Electron spin resonance
4) radical stability and reactivity
5) reaction of radicals. reactions of halogen radicals
6) reactions of oxygen and nitrogen radicals
7) Radical addition reaction. addition of HX
8) Midterm
9) addition of carbon, sulfur and fosforus radicals
10) Polymerisation of alkenes
11) radical polymerization reactions
12) radical aromatic substituted reactions
13) radical aromatic substituted reactions
14) radical coupling and disproportion reactions
15) radical coupling and disproportion reactions
16) Final
Recommended or Required Reading
Planned Learning Activities and Teaching Methods
1) Lecture
2) Question-Answer
3) Discussion
4) Drill and Practice
5) Self Study
6) Problem Solving
Assessment Methods and Criteria
Contribution of Midterm Examination to Course Grade |
30% |
|---|---|
Contribution of Final Examination to Course Grade |
70% |
Total |
100% |
Language of Instruction
Turkish
Work Placement(s)
Not Required